聚合物多層次結(jié)構(gòu)中稀土絡合物的光譜性質(zhì)
定 價：48 元
- 作者：張其錦
- 出版時間：2009/1/1
- ISBN：9787312022517
- 出 版 社：中國科學技術(shù)大學出版社
- 中圖法分類：O614.33
- 頁碼：197
- 紙張：
- 版次：1
- 開本：16開
《聚合物多層次結(jié)構(gòu)中稀土絡合物的光譜性質(zhì)（英文版）》將具有不同結(jié)構(gòu)的稀土摻雜聚合物作為研究對象，從理論和實驗的角度對這些聚合物進行了光譜分析、摻雜基質(zhì)結(jié)構(gòu)設計、發(fā)光性質(zhì)與各層次結(jié)構(gòu)的關(guān)系以及光量子調(diào)控等多方面的研究，包括各種新穎結(jié)構(gòu)的設計和由其產(chǎn)生的各種特異性質(zhì)。其中光量子調(diào)控是迅速發(fā)展的寬帶通訊領(lǐng)域的關(guān)鍵技術(shù)，相應的基礎(chǔ)和應用基礎(chǔ)研究已形成一個由聚合物科學和光子學交叉而成的新興學科——光子學聚合物科學。書中介紹的發(fā)光調(diào)控、三維光學存儲和稀土摻雜聚合物光纖的光放大性質(zhì)等均為光子學聚合物領(lǐng)域的最新進展。雖然《聚合物多層次結(jié)構(gòu)中稀土絡合物的光譜性質(zhì)（英文版）》是非常專業(yè)的學術(shù)專著，但是通過閱讀，讀者也能從中了解這一新興交叉學科的概況。書中還列出了相關(guān)原始文獻以滿足感興趣的讀者進一步了解相關(guān)內(nèi)容的需要。聚合物是通過化學鍵將小分子連接起來而形成的長鏈狀大分子。由這種分子聚集形成的固體材料具有多層次的物質(zhì)結(jié)構(gòu)，這些結(jié)構(gòu)會影響摻雜其中的各種功能基團的性質(zhì)。
本書將具有不同結(jié)構(gòu)的稀土摻雜聚合物作為研究對象，從理論和實驗的角度對這些聚合物進行了光譜分析、摻雜基質(zhì)結(jié)構(gòu)設計、發(fā)光性質(zhì)與各層次結(jié)構(gòu)的關(guān)系以及光量子調(diào)控等多方面的研究，包括各種新穎結(jié)構(gòu)的設計和由其產(chǎn)生的各種特異性質(zhì)。
Chapter 1 Synthesis and characterizationof rare earth complex doped polymers
1.1 Synthesis of rare earth complex doped polymer
1.2 Uniformity and thermal stability of rare earth complex doped polymer
1.2.1 X-ray diffraction of rare earth complex doped
1.2.2 Near-field scanning analysis of rare earth complex doped
1.2.3 Thermal properties of rare earth complex doped PMMA
Chapter 2 Spectroscopic properties of rare earth complex doped PMMA and their Judd-Ofelt treatment
2.1 The theory of spectroscopic analysis
2.1.1 Energy level analysis and nephelauxetic effect of rare earth complexes
2.1.2 Judd-Ofelt Theory
2.2 Spectroscopic analysis of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 in PMMA
2.2.1 Energy level analysis and nephelauxetic effect of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 in MMA and
2.2.2 Radiative properties of Nd（DBM）3Phen and Nd（DBM）3 （TPPO）2 doped PMMA
2.3 Spectroscopic analysis of Eu complexes in PMMA
2.3.1 Fluorescence of Eu complexes in PMMA
2.3.2 Radiative properties of Eu complexes in PMMA
2.4 Spectroscopic analysis of Er complexes in PMMA
2.4.1 Fluorescence of Er complexes in PMMA
2.4.2 Energy level analysis and nephelauxetic effect of Er（DBM）3 （TPPO）2 in PMMA
2.4.3 Radiative properties of Er（DBM）3 （TPPO）2 doped PMMA
2.5 Spectroscopic analysis of Pr complexes in PMMA
2.5.1 Fluorescence of Pr complexes in PMMA
2.5：2 Energy level analysis and Nephelauxetic effect of
Pr（DBM）3Phen and Pr（DBM）3 （TPPO）2 in PMMA
2.5.3 Radiative properties of Pr（DBM）3 （TPPO）2 doped PMMA
2.6 Spectroscopic analysis of Sm complexes in PMMA
2.6.1 Fluorescent analysis of Sm complexes in MMA
2.6.2 Energy level analysis and nephelauxetic effect of Sm（TTA）a （TPPO）2 in MMA and PMMA
2.6.3 Radiative properties of Sm（DBM）a （TPPO）2 in MMA and PMMA
Chapter 3 Rectification of excitation with bathochromic shift during emission measurement of Eu complexes
3.1 Bathochromic shift during fluorescence measurement
3.2 Theoretical model for treatment of Bathochromic shift
3.3 Prediction of best exciting wavelength for fluorescence measurement
Chapter 4 Fluorescence enhancing of rare earth complexes in PMMA
4.1 Fluorescence enhancement of Eu（DBM）3Phen codoped with the other rare earth complexes in PMMA
4.2 Fluorescence enhancement of Sm（DBM）3Phen codoped with other rare earth complexes in PMMA
4.3 Model for luminescence enhancement in PMMA codoped with two kinds of rare earth complexes
4.3.1 Intra-molecular energy transfer within each complex
4.3.2 Inter-molecular energy transfer between complexes
4.3.3 Quantitative model for luminescence enhancement of Eux Tby-PMMA
Chapter 5 Effects of synergetic ligands on radiative properties of Eu（TTA）3 nL doped PMMA and LB films
5.1
……
7.1 J-aggregates of rare earth complexes formed on the surface of silver nanoparticles
7.2 Effects of Ag colloidal nanoparticles on luminescent properties of Eu（ l]I） -diketone
7.3 Nanocomposite composed of Eu（TTA）3Bipy/Tb（TTA）3Bipy/Silver Nanoparticles
Chapter 8 Modulation in luminescence of rare earth complexes doped in photo-responsive polymer
8.1 Photo-induced optical anisotropy and polarized emission of europium complex doped azobenzene polymer film
8.2 Reversible modulation in fluorescence intensity of a single vesicle composed of diblock azo-copolymer and Eu （DBM） 3 Phen
Chapter 9 Polymer optical fibers doped with rare earth complexes
9.1 Gradient refractive index distribution of POF
9.1.1 Qualitative description of interfacial-gel polymerization
9.1.2 Diffusion process given by free volume theory
9.1.3 Gradient refractive index distribution of undoped POF
9.1.4 Gradient refractive index distribution of rare earth complex doped POF
9.2 Design and fabrication of SCPOF preform doped with rare earth complexes
9.3 Optical amplification of rare earth complexes doped SI POF
Postscript
References
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